Surface hydrophobicity and acidity effect on alumina catalyst in catalytic methanol dehydration reaction

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Surface hydrophobicity and acidity effect on alumina catalyst in catalytic methanol dehydration reaction

BACKGROUND Methanol to dimethyl ether (MTD) is considered one of the main routes for the production of clean bio-fuel. The effect of copper loading on the catalytic performance of different phases of alumina that formed by calcination at two different temperatures was examined for the dehydration of methanol to dimethyl ether (DME). RESULTS A range of Cu loadings of (1, 2, 4, 6, 10 and 15% Cu...

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DME Synthesis over MSU-S Catalyst through Methanol Dehydration Reaction

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dme synthesis over msu-s catalyst through methanol dehydration reaction

msu-s mesoporous catalyst with [sio2]/[al2o3] ratio of 55 was synthesized using tetrapropylammonium hydroxide (tpaoh) as a structure directing agent and hexadecyltrimethylammonium bromide (ctab) as a surfactant. the catalytic activity of the calcined sample was evaluated for the dehydration of methanol to dimethyl ether (dme) in a vertical fixed bed microreactor at a weight hurly space velocity...

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The Catalytic Cracking of Hydrocarbons in a Riser Simulator: The Effect of Catalyst Accessibility and Acidity

_____________________________________________________________ Different catalysts based on Y-zeolite, ZSM-5 and amorphous kaolin were prepared and characterized. The catalytic cracking of 1,3,5-triisopropylbenzene (1,3,5-TIPB), 1,4diisopropylbenzene (1,4-DIPB) and n-dodecane were used to investigate the effect of catalyst nature on the catalytic performance. Cracking the largest molecule (1,3,5...

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Intrinsic Kinetics of Methanol Dehydration over Al2O3 Catalyst

Dehydration of methanol to dimethyl ether (DME) over a commercial Al2O3 catalyst was studied in an isothermal integral fixed bed reactor. The experiments were performed on the temperature interval 513-613 K, liquid hourly space velocity (LHSV) of 0.9-2.1h, pressures between 0.1 and 1.0 MPa. The effect of different operation conditions on the dehydration of methanol was investigated in a laborat...

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ژورنال

عنوان ژورنال: Journal of Chemical Technology & Biotechnology

سال: 2017

ISSN: 0268-2575

DOI: 10.1002/jctb.5371